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Lead(II) iodide

Lead(II) iodide

CAS: 10101-63-0

Molecular Formula: I2Pb

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Lead(II) iodide - Names and Identifiers

Name Lead(II) iodide
Synonyms LT-S9147
Leadiodide
lead diiodide
Lead(II)iodide
LEAD(II) IODIDE
Lead(II) iodide
Lead (II) iodide
Lead(II) diiodide
LEADIODIDE,REAGENT
Leadiodidecrystalline
Lead iodide anhydrous
Leadiodideyellowpowder
diiodo-lambda~2~-plumbane
lead(ii) iodide, ultra dry
CAS 10101-63-0
EINECS 233-256-9
InChI InChI=1/2HI.Pb.4H/h2*1H;;;;;/q;;+2;;;;/p-2/r2HI.H4Pb/h2*1H;1H4/q;;+2/p-2
InChIKey RQQRAHKHDFPBMC-UHFFFAOYSA-L

Lead(II) iodide - Physico-chemical Properties

Molecular FormulaI2Pb
Molar Mass461.01
Density6.16g/mLat 25°C(lit.)
Melting Point402°C(lit.)
Boling Point954°C(lit.)
Flash Point954°C
Water SolubilityPartially soluble in water. Freely soluble in sodium thiosulfate solution. Soluble in concentrated solutions of alkali iodides. Insoluble in alcohol and cold HCl.Soluble in concentrated solutions of a
Solubility Soluble in concentrated solutions of alkali iodides and sodium thiosulfate. Insoluble in alcohol and cold hydrochloric acid.
AppearanceYellow powder
Specific Gravity6.16
ColorYellow to orange
Exposure LimitACGIH: TWA 0.05 mg/m3; TWA 0.01 ppmNIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3
Solubility Product Constant(Ksp)pKsp: 8.01
Maximum wavelength(λmax)['539nm(neat)(lit.)']
Merck14,5411
Storage ConditionKeep in dark place,Inert atmosphere,Room temperature
StabilityStable. May discolour upon exposure to light.
SensitiveLight Sensitive
MDLMFCD00011163
Physical and Chemical PropertiesLead iodide is a bright yellow heavy powder or hexagonal scale crystal, the molecular formula is PbI, no smell, high melting point and boiling point. At room temperature, a bright yellow odorless crystalline solid turned orange and red after heating. The solubility in water increases with increasing temperature.
lead iodide is used as a precursor material for the fabrication of high-efficiency solar cells, and PbI2 can also be used as a high-energy photon detector for gamma rays and X-rays. Lead iodide has also been used as a pigment called yellow iodide, but has been eliminated due to toxicity and instability.
UseFor the pharmaceutical industry

Lead(II) iodide - Risk and Safety

Risk CodesR61 - May cause harm to the unborn child
R20/22 - Harmful by inhalation and if swallowed.
R33 - Danger of cumulative effects
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62 - Possible risk of impaired fertility
Safety DescriptionS53 - Avoid exposure - obtain special instructions before use.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDsUN 2291 6.1/PG 3
WGK Germany3
FLUKA BRAND F CODES8
TSCAYes
HS Code28276000
Hazard Class6.1
Packing GroupIII

Lead(II) iodide - Introduction

Soluble in potassium iodide, sodium iodide and alkali solution, insoluble in water and alcohol, toxic.
Last Update:2022-10-16 17:11:28

Lead(II) iodide - Reference Information

NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
solubility in water (g/100ml) dissolution grams per 100ml of water at different temperatures (℃): 4.4 × 10-2/30 ℃;5.6 × 10-2/10 ℃;6.9 × 10-2/20 ℃;9 × 10-2/30 ℃;0.124g/40 ℃ 0.193g/60 ℃;0.294g/80 ℃;0.42g/100 ℃
use pharmaceutical industry, photography industry, bronze plating.
used in pharmaceutical industry
production method dissolving 260g of analytically pure potassium iodide in 600mL of water and heating. 300g of analytically pure lead acetate trihydrate is dissolved in 600mL of water, and the solution is slowly added to the hot solution of potassium iodide under stirring. After washing 8~10 times with water pouring method, the resulting precipitate was filtered with Brinell funnel. Then spread the precipitate on waterproof paper, dry it at 80~90 ℃, and then grind it into fine powder in a ventilated place. The yield is 365g, and the yield is close to 100%. The resulting lead iodide precipitate can be recrystallized in glacial acetic acid to form lead iodide crystals.
category toxic substances
flammability hazard characteristics non-combustible; hyperthermal decomposition; combustion releases toxic iodide smoke
storage and transportation characteristics warehouse low temperature, ventilation, drying
fire extinguishing agent water, carbon dioxide, dry powder, sand
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-10 22:29:15
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View History
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